Effects of nanoparticles on wettability: A review on applications of nanotechnology in the enhanced Oil recovery

Document Type : Review


Young Researchers and Elite Club, Omidieh Branch, Islamic Azad University, Omidieh, Iran.



Recently, a renewed interest arises in the application of nanotechnology for the upstream petroleum industry. In particular, adding nanoparticles to fluids may drastically benefit enhanced oil recovery and improve well drilling, by changing the properties of the fluid, rocks wettability alteration, advanced drag reduction, strengthening the sand consolidation, reducing the inter-facial tension and increasing the mobility of the capillary trapped oil. In this study, we focus on roles of nanoparticles on wettability. This paper therefore focuses on the reviews of the application of nano technology in chemical flooding process in oil recovery and reviews the Application Nano in the Polymer and Surfactant flooding on the Wettability process.


Main Subjects

[1]  Das S. K., Choi S. U. S., Yu W., Pradeep T., (2008), Nanoûuids Science and Technology. John Wiley & Sons, Inc Publishing,Hoboken. NJ, ISBN: 0470074736.
[2]  Hendraningrat L., Li S., Torsæter O., (2013), A coreûood investigation of nanoûuid enhanced oil recovery. J. Petrol. Sci. Eng. 111: 128-138.
[3]  Engese B., (2012), The Potential of Hydrophilic Silica Nanoparticles for EOR Purposes: A Literateur Review and an Experimental Study. Norway: Department of Petroleum Engineering and Applied Geophysics, Norwegian University of Science and Technology. Trondheim, Master thesis.
[4]  Kanj M. Y., Funk J. J., Al-Yousif Z., (2009), Nanofluid coreflood experiments in the ARAB-D, SPE Saudi Arabia Section Technical Symposium and Exhibition, AlKhobar, SaudiArabia.
[5]  Cheraghian G., Khalili Nezhad S., Kamari M., Hemmati M., Masihi M., Bazgir S., (2014), Adsorption polymer on reservoir rock and role of the nanoparticles, clay and SiO2. Int. Nano Lett. 4: 114-117.
[6]  Ju B., Fan T., Ma M., (2006), Enhanced Oil Recovery by Flooding with Hydrophilic. Nanopart.  China Particuol. 4: 41-46.
[7]  Miranda C. R., De Lara L. S., Tonetto B. C., (2012), Stability and mobility of functionalized silica nanoparticles for enhanced oil recovery application. Soc. Pet. Eng. SPE 157033-MS.
[8]  Roustaei A., Saffarzadeh S., Mohammadi M., (2013), An evaluation of modiûed silica nanoparticles. effciency in enhancing oil recovery of light and intermediate oil reservoirs. Egyp. J. Pet. 22: 427-433.
[9]  Cheraghian G., Tardasti S., (2012), Improved Oil Recovery by the Efficiency of Nano-particle in Imbibition Mechanism. 74th EAGE Conference and Exhibition incorporating EUROPEC.
[10] Hendraningrat L., Li S., Torsæter O., (2013), Enhancing oil recovery of low-permeability berea sandstone through optimized nanoûuids concentration. In: SPE enhanced oil recovery conference, Kuala Lumpur, Malaysia.
[11] Wasan D. T., Nikolov A., (2003), Spreading of nanofluids on solids. Nature. 423: 156-159.
[12] Wasan D. T., Nikolov A., Kondiparty K., (2011), The wetting and spreading of nanofluids on solids: Role of the structural disjoining pressure. Curr. Opin. Colloid Interface Sci. 16: 344-349.
[13] Chengara A., Nikolov A., Wasan D. T., Trokhymchuck A., Henderson D., (2004), Spreading of nanofluids driven by the structural disjoining pressure gradient. J. Colloid Interf. Sci. 280: 192-201.
[14] Ju B., Tailiang F., Mingxue M., (2006), Enhanced oil recovery by flooding with hydrophilic nanoparticles. China Particuol. 4: 41-46.
[15] Ogolo N. A., Olafuyi O. A., Onyekonwu M. O., (2012), Enhanced oil recovery using nanoparticles. Soc. Pet. Eng. SPE 160847-MS.
[16] Hendraningrat L., Torsæter O., (2014), Metal oxidebased nanoparticles: revealing their possibility to enhance the oil recovery at different wettability systems. Appl. Nano Sci. Springer.
[17] Torsater O., Li S., Hendraningrat L., (2013), Effect of Some Parameters Influencing Enhanced Oil Recovery Process using Silica Nanoparticles, SPE Reservoir Characterization and Simulation Conference and Exhibition. Abu Dhabi, UAE, 16-18 September.
[18] Yuan W., Liu X., Wei H., Liu J., Yang H., Hu S., Li Y., Wang D., (2010), Research and application effect of polymeric microsphere in Wen-10 of Sinopec Zhongyuan Oil ûeld. Inner Mong. Petrochem. 12: 122-126.
[19] Li X., Ying Z., Jia Y., Liu X., Yang T., Ma L., (2012), Application of nanosphere deep proûle  control and displacement technology in Chanqing oilûeld. Oil Field Chem. 29: 13-16.
[20] Tian Y., Wang L., Tang Y., Liu C., Ma C., Wang T., (2012), Research and application of nano polymer microspheres diversion technique of deep fluid. Soc. Pet. Eng. SPE 156999-MS.
[21] Hamedi Sh. Y., Babadagli T., (2010), Effects of nano sized metals on viscosity reduction of heavy oil/bitumen during thermal applications, Canadian Unconventional Resources & International Petroleum Conference Held in Calgary, Alberta, Canada, 19-21 October.
[22] Hendraningrat L., Engeset B., Suwarno S., Torsæter O., (2012), Improved oil recovery by nanofluids flooding: an experimental study. In: SPE Kuwait international petroleum conference and exhibition Kuwait city, Kuwait.
[23] Pourafshary P., Azimipour S. S., Motamedi P., Samet M., Taheri S. A., Bargozin H., Hendi S. S., (2009), Priority assessment of the investment in development of nanotechnology in upst ream petroleum industry. In: Proceedings of the Saudi Arabia Sect ion Technical Symposium and Exhibition. A1Khobar, Saudi Arabia, SPE No. 126101-MS.
[24] Skauge T., Hetland S., Spildo K., SkaugeA., (2010), Nano- Sized Particles for EOR , SPE 129933, SPE Improved Oil Recovery Symposium, Oklahoma, USA, 24-28 April.
[25] Cheraghian G., (2015), Thermal Resistance and Application of Nanoclay on Polymer Flooding in Heavy Oil recovery. Petrol. Sci. Tech. 33: 1410-1413.
[26] Cheraghian G., Khalili Nezhad S., Kamari M., Hemmati M., Masihi M., Bazgir S., (2014), Effect of nanoclay on improved rheology properties of polyacrylamide solutions used in enhanced oil recovery. J. Petrol. Explor. Prod. Tech. 5: 189-196.
[27] Le N. Y. T, Pham D. K., Le K. H., Nguyen P. T., (2011), Design and screening of synergist ic blends of SiO2 nanoparticles and surfactants for enhanced oil recovery in high-temperature reservoirs. J. Adv. Nat. Sci. 2: 35013-35019.
[28] Abidina A. Z., Puspasaria T., Nugroho W. A., (2012), Polymers for Enhanced Oil Recovery Technology. Proced. Chem. 4: 11-16.
[29] Du Y., Guan L., (2004), Field-scale polymer flooding: lessons learnt and experiences gained during past 40 years. SPE 91787 presented at SPE international petroleum conference, Puebla, Mexico. 8-9 November.
[30] Wang J., Dong M., (2009), Optimum effective viscosity of polymer solution for improving heavy oil recovery. J. Petrol. Sci. Eng. 67: 155-158.
[31] Sheng J., (2011), Modern chemical enhanced oil recovery. Gulf Profession Publishing 101.206.
[32] Wang D., Cheng J., Wu J., Wang Y., (2002), Producing by polymer ûooding more than 300 million barrels of oil what experiences have been learnt. SPE 77872 presented at Asia Paciûc oil and gas conference and exhibition, Melbourne, Australia.
[33] Wang D., Zhao L., Cheng J., Wu J., (2003), A ctual field  data show that production costs of polymer flooding can be lower than water flooding. SPE 84849 presented at improved oil recovery conference in Asia Pacific, Kuala Lumpur, Malaysia, 20-21 October 2003. Publishing 101.
[34] Wang D. M., Xia H. F., Liu Z. C., Yang Q. Y., (2001), Study of the mechanism of polymer solution with viscoelastic behavior increasing microscopic oi l displacement efficiency and the Forming of Steady .Oil Thread. Flow Channels, SPE Asia Pacific Oil and Gas Conference and Exhibition, 17-19 April, Jakarta.
[35] Guo X. H., Li D. W., Tian J., Liu Y. Z., (1999), Pilot test of xanthan gum ûooding in Shengli oilûeld. In: SPE 57294 presented at SPE Asia Paciûc improved oil recovery conference, Kuala Lumpur.
[36] Ye Z. B., Gou G. J., Gou S. H., Jiang W. C., Liu T. Y., (2013), Synthesis and characterization of a water-soluble sulfonates copolymer of acrylamide and N-Allylbenzamide as enhanced oil recovery chemical. J. Appl. Polym. Sci. 128: 2003-2011.
[37] Shiran B. S., Skauge A., (2013), Enhanced oil recovery (EOR) by combined low salinity water/polymer flooding. Energy Fuels. 27: 1223-1235.
[38] Zhong C., Huang R., Zhang X., Dai H., (2007), Synthesis, characterization, and solution properties or an acrylamidebased terpolymer with butyl styrene. J. Appl. Polym. Sci. 103: 4027-4038.
[39] Ye Z., Qin X., Lai N., Peng Q., Li X., Li C., (2013), Synthesis and Performance of an Acrylamide Copolymer Containing Nano-SiO2 as Enhanced Oil Recovery Chemical. Hind. Pub. Corp. J. Chem. 2013, Article ID 437309, 10 pages.
[40] Chang S. H., Chung I. J., (1991), Effect of shear flow on polymer desorption and latex dispersion stability in the presence of adsorbed polymer. Macromol. 24: 567-571.
[41] Xue L., Agarwal U. S., Lemstra P. J., (2005), Shear degradation resistance of star polymers during elongational ûow. Macromol. 38: 8825-8832.
[42] Wu Z., Yu J., Cheng T., Yue X., Yang H., (2014) Effect of viscosity and interfacial tension of surfactant.polymer ûooding on oil recovery in high-temperature and highsalinity reservoirs. J. Petrol. Explor. Prod. Technol. 4: 9-16.
[43] Yadali Jamaloei B., Kharrat R., Ahmadloo F., (2009), Selection of proper criteria in flow behavior characterization of low tension polymer flooding in heavy oil reservoirs. SPE Kuwait international petroleum conference and exhibition. Kuwait City, Kuwait.
[44] Raterman K. T., Kremesec Jr., V. J., Suffridge F. E. (1988), Evaluation of low-concentration surfactant ûooding in the absence of mobility control agents. SPE/DOE Paper No. 17394. SPE/DOE Enhanced Oil Recovery Symposium, Tulsa, Oklahoma, April 17-30.
[45] Sanz C. A., Pope G. A., (1995), Alcohol-free chemical ûooding: From surfactant screening to coreûood design. SPE Paper No. 28956. SPE International Symposium on Oil field Chemistry, San Antonio, Texas, February 14-17.
[46] Yang H. D., Wadleigh E. E., (2000), Dilute surfactant IOR. Design improvement for massive, fractured carbonate applications. SPE Paper No. 59009. 2000 SPE International Petroleum Conference and Exhibition, Villa Hermosa, Mexico, February 1-3.
[47] Sanele S., Yortsos Y. C., (1986), A note on the application of the theory of coherence to surfactant flooding. SPE Reserv. Eng. 1: 23-28.
[48] Hornof V., Morrow, N. R. (1987), Gravity effects in the displacement of oil by surfactant solution. SPE Paper No. 13573. SPE Reserv. Eng. 2: 627-633.
[49] Hematpour H., Arabjamloei R., Nematzadeh M., Esmaili H., Mardi M., (2012), An Experimental Investigation of Surfactant Flooding Efficiency in Low Viscosity Oil Using a Glass Micromodel. Energy Sour. Part A.: Recovery, Utilization, and Environmental Effects. 34: 1745-1758.
[50] Esmaeilzadeh P., Hosseinpour N., Bahramian A., Fakhroueian Z., Arya S., (2014), Effect of ZrO2
nanoparticles on the interfacial behavior of surfactant solutions at air.water and n-heptane. water interfaces. Fluid Phase Equilibria. 361: 289- 295.
[51] Le N., Pham D. K., Le K. H., Nguyen P. T., (2011), Design and Screening of Synergistic Blends of SiO2 Nanoparticles and Surfactants for Enhanced Oil Recovery in High-Temperature Reservoirs. Adv. Natural Sci.: Nanosci. Nanotech. 2: 17: 45-49
[52] Suleimanov B. A., Ismailov F. S., Veliyev E. F., (2011), Nanoûuid for Enhanced Oil Recovery. J. Pet. Sci. Eng. 78: 431-437.
[53] Lake L.W., (1989), Enhanced Oil Recovery. Prentice-Hall, Inc., Upper Saddle River, New Jersey.
[54] Austad T., Fjelde I., Veggeland K., Taugbol K., (1994), Physicochemical principles of low tension polymer flood. J. Petrol. Sci. Eng. 10: 255-269.
[55] Taugbel K., Ly T. V., Austad T., (1995), Chemical flooding of oil reservoirs 3.Dissociative surfactant-polymer interaction with a positive effect on oil recovery. Colloids Surf. A: Physicochem. Eng. Aspects. 10: 83-90.
[56] Breuer M. M., Robb I. D., (1972), Interactions between macromolecules and detergents. Chem. Ind. 54: 530-535.
[57] Goddard E. D., (1986), Interactions between macromolecules and detergents. Colloids Surf. 1: 255-300.
[58] Piculell L., Lindman B., (1992), Association and segregation in aqueous polymer/polymer, polymer/
surfactant. Adv. Colloid Interf. Sci. 4: 149-178.
[59] Lindman B., Thalberg K., Goddard E. D., Ananthapadmanabhan K. P. (Eds.), (1993), Interactions of
Surfactants with Polymers and Proteins, CRC Press, Boca Raton. 203-276.
[60] Aoudia M., Al-Shibli M. N., Al-Kasimi L. H., Al-Maamari R., Al-Bemani A., (2006), Novel surfactants for ultralow interfacial tension in a wide range of surfactant concentration and temperature. J. Surfac. Deterg. 9: 287-293.
[61] Cui Z., DU X., Pei X., Jiang J., Wang F., (2012), Synthesis of didodecylmethylcarboxyl betaine and its application in surfactant. polymer flooding. J. Surfac. Deterg. 15: 685-694.
[62] Rosen M. J., Wang H., Shen P., Zhu Y., (2005), Ultralow interfacial tension for enhanced oil recovery at very low surfactant concentrations. Langmuir. 21: 3749.3756.
[63] Ferdous S., Ioannidis M. A., Henneke D. E., (2012), Effects of temperature, pH, and ionic strength on the adsorption of nanoparticles at liquid. liquid interfaces. J. Nanopart. Res. 14: 850-855.
[64] Gong H., Guiying X., Zhu Y., Wang Y., Dan W., Niu M., Wang L., Guo H., Wang H., (2009), Influencing factors on the properties of complex systems consisting of hydrolyzed polyacrylamide/triton x-100/cetyl trimethylammonium bromide: viscosity and dynamic interfacial tension studies. Energy Fuels. 23: 300-305.
[65] Cao Y., Zhao R., Zhang L., Xu Z., Jin Z., Luo L., Zhang L., Zhao S., (2012), Effect of electrolyte and temperature on interfacial tensions of alkylbenzene sulfonate solutions. Energy Fuels. 26: 2175-2181.
[66] Zhang H., Dong M., Zhao S., (2012), Experimental study of the interaction between NaOH, surfactant, and polymer in reducing court heavy oil/brine interfacial tension. Energy Fuels. 26: 3644-3650.
[67] Morrow N. R., Lim H. T., Ward J. S., (1984), Effect of crude-oil-induced wettability changes on oil recovery. 59th Annual Society of Petroleum Engineers of AIME Technical Conference, Houston, Texas (paper SPE 13215).
[68] Morrow N. R., (1990), Wettability and its effect on oil recovery. J. Pet. Tech. 24: 1476-1485.
[69] Anderson W. G., (1987), Wettability literature survey-Part 6: The effects of wettability on waterflooding. J. Pet. Tech. 39: 1605-1622.
[70] Rao D., Girard M., Sayegh S., (1992), The influence of reservoir wettability on waterûood and miscible ûood performance. J. Canad. Petrol. Tech. 31: 47-55.
[71] Jadhunandan P. P., Morrow N. R., (1995), Effect of wettability on waterûood recovery for crude-oil/brine/rock systems. SPE Reservoir Eng. 10: 40-46.
[72] Zhou X., Morrow N. R., Ma S., (2000), Interrelationship of wettability, initial water saturation, aging time, and oil recovery by spontaneous imbibition and waterflooding. SPE Journal. 5: 199-207.
[73] Dwarakanath V., Jackson R. E., Pope G. A., (2002), Influence of wettability on the recovery of NAPLs from alluvium. Environmental Science and Technology. 36: 227-231.
[74] Hatiboglu C., Babadagli T., (2006), Primary and secondary oil recovery from different-wettability rocks by countercurrent diffusion and spontaneous imbibition. SPE/DOE Symposium on Improved Oil Recovery, Tulsa, Oklahoma (paper SPE 94120).
[75] Johannesen E. B., Graue A., (2007), Mobilization of remaining oil. Emphasis on capillary number and wettability. Int. Oil Conf. Exhibition in Mexico, Veracruz, Mexico (paper SPE 108724).
[76] Johannesen E., Graue A., (2007), Systematic investigation of waterflood reducing residual oil saturations by increasing differential pressures at various wettabilities. Offshore Europe, Aberdeen, Scotland, UK (paper SPE 108593).
[77] Yefei W., Huaimin X., Weizhao Y., Baojun B., Xinwang S., Jichao Z., (2011), Surfactant induced reservoir wettability alteration: Recent theoretical and experimental advances in enhanced oil recovery. Pet. Sci. 8: 463-476.
[78] Morrow N. R., Lim H. T., Ward J. S., (1986), Effect of crude-oil-induced wettability changes on oil recovery. SPE Form. Eval. (Feb.), 89-103.
[79] Cuiec L. E., (1990), Evaluation of reservoir wettability and its effect on oil recovery. In: Morrow, N.R. (Ed.), Interfacial Phenomena in Oil Recovery. Marcel Decker, New York, 375-391.
[80] Kowalewski E., Holt T., Torsaeter O., (2002), Wettability alterations due to an oil soluble additive. J. Petrol. Sci. Eng. 6: 443-452, 2015 (Special Issue for NCNC, Dec. 2014, IRAN )
[81] Ju B., Fan T., (2009), Experimental study and mathematical model of nanoparticle transport in porous media. Powder Technol. 192: 195.202.
[82] Yu H., Kotsmar C., Yoon K. Y., Ingram D. R., Johnston K. P., Bryant S. L., Huh C., (2010), Transport and retention of aqueous dispersions of paramagnetic nanoparticles in reservoir rocks. In: SPE improved oil recovery symposium, Tulsa, OK, USA.
[83] Onyekonwu M. O., Ogolo N. A., (2010), Investigating the use of nanoparticles in enhancing oil recovery. Paper No. 140744-MS, Nigerian Annual International Conference and Exhibition, Tinapa-Calabar, Nigeria, July 31.August 7.
[84] Roustaei A., Bagherzadeh H., (2015), Experimental investigation of SiO2 nanoparticles on enhanced oil recovery of carbonate reservoirs. J. Petrol. Explor. Prod. Tech. 5: 27-33.
[85] Safari M., (2014), Variations in Wettability Caused by Nanoparticles. Petrol. Sci. Tech. 32: 1505-1511.
[86] Zhang T., Davidson A., Brytant S. L., Huh C., (2010), Nanoparticle-Stabilized Emulsions forApplication in Enhanced Oil Recovery, SPE Improved Oil Recovery Symposium, Tulsa, Oklahoma, USA, 24-28 April 2010. 18.
[87] Bishan J., Tailang F., Mingxua M., (2005), Enhanced oil recovery by flooding with hydrophilic nanoparticles. China Particuol. 4: 41.46.
[88] Ju B., Luan Z., Wu Z., Lü G., (2001), A study of removal of organic formation damage by experiments and modeling approaches. Proceedings of the SPE Asia Pacific Oil and Gas Conference and Exhibition. Jakarta, Indonesia.
[89] Van Oss C. J., Giese R. F., (1995), The hydrophilicity and hydrophobilicity of clay minerals. Clays Clay Miner. 43: 474-477.
[90] Wu S., Firoozabadi A., (2010), Permanent alteration of porous media wettability from liquid-wetting to intermediate gas-wetting. Transp. Porous. Media. 85: 189-213.
[91] Maghzi A., Mohebbi A., Kharrat R., Ghazanfari M. H., (2011), Pore-Scale Monitoring of  Wettability Alteration by Silica Nanoparticles During Polymer Flooding to Heavy Oil in a Five-Spot Glass Micromodel. Transp Porous Med. 87: 653.664.
[92] Ershadi M., Alaei M., Rashidi A., Ramazani A., Khosravani S., (2015), Carbonate and sandstone reservoirs wettability improvement without using surfactants for Chemical Enhanced Oil Recovery (C-EOR). Fuel. 153: 408-415.
[93] Parvazdavani M., Masihi M., Ghazanfari M. H., Sherafati M., Mashayekhi L., (2012), Investigation of the Effect of Water Based Nano-Particles Addition on Hysteresis of Oil and-Water Relative Permeability Curves. SPE 157005. The SPE International Oilfield Nanotechnology Conference held in Noordwijk, The Netherlands, 12.14 June.
[94] Cheraghian G., Khalili Nezhad S., (2015), Effect of Nanoclay on Heavy Oil Recovery during Polymer Flooding. J. Pet. Sci. Tech. 33: 999-1007.
[95] Cheraghian G., (2015), An experimental study of a surfactant polymer for enhanced heavy-oil recovery using a glass micromodel by adding nanoclay. J. Pet. Sci. Tech. 33: 13-14.
[96] Joonaki E., Ghanaatian S., (2014), The Application of Nanofluids for Enhanced Oil Recovery: Effects on Interfacial Tension and Coreflooding Process. J. Pet. Sci. Tech. 32: 2599-2607.
[97] Mohammadi M., Moghadasi J., Naseri S., (2014), An Experimental Investigation of Wettability Alteration in Carbonate Reservoir Using ã-Al2O3 Nanoparticles . Irani. J. Oil & Gas Sci. Tech. 3: 18-26.
[98] Alvarado V., Manrique E., (2010), Enhanced Oil Recovery: An Update Revi. Energ. 3: 1529-1575.